OK, so if the injector turns off when the #60 terminal is de-pinned (and all the other engine ECU terminals are still connected), then that would point to the issue being within the engine ECU as you have said

(I'm still quite surprised to be honest!

)
The next thing I would be doing is checking where along the line the #60 terminal is being grounded, i.e. measure the voltage at the #60 transistor base... unsolder the #60 transistor and see if the collector is grounded... etc (It sounds like you've got a pretty good handle on fault finding, so prbly don't need my help here

).
Leaking caps within older Toyota ECUs is quite common unfortunately. Defiantly a good idea to replace. Ear cleaners dipped in acetone are good for cleaning up the capacitor residue / conformal coating / flux left over from when you solder the new caps in also FYI.
Cheers
Wilbo
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